In 1830, Michael Faraday showed that if electricity is passed through a solution of an electrolyte, chemical reactions occurred at the electrodes, which resulted in the liberation and deposition of matter at the electrodes. He formulated certain laws which you will study in class XII. These results suggested the particulate nature of electricity.
An insight into the structure of atom was obtained from the experiments on electrical discharge through gases. Before we discuss these results we need to keep in mind a basic rule regarding the behaviour of charged particles : “Like charges repel each other and unlike charges attract each other”.
In mid 1850s many scientists mainly Faraday began to study electrical discharge in partially evacuated tubes, known as cathode ray discharge tubes. It is depicted in


A cathode ray tube is made of glass containing two thin pieces of metal, called electrodes, sealed in it. The electrical discharge through the gases could be observed only at very low pressures and at very high voltages. The pressure of different gases could be adjusted by evacuation. When sufficiently high voltage is applied across the electrodes, current starts flowing through a stream of particles moving in the tube from the negative electrode (cathode) to the positive electrode (anode). These were called cathode rays or cathode ray particles. The flow of current from cathode to anode was further checked by making a hole in the anode and coating the tube behind anode with phosphorescent material zinc sulphide . When these rays, after passing through anode, strike the zinc sulphide coating, a bright spot on the coating is developed (same thing happens
in a television set).