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Physical chemistry LowerSixth

CHAPTER I: STRUCTURE OF ATOM

VI. Charge to Mass Ratio of Electron

In 1897, British physicist J.J. Thomson measured the ratio of electrical charge (e) to the mass of electron (me) by using cathode ray tube and applying electrical and magnetic field perpendicular to each other as well as to the path of electrons (Fig. 2.2). Thomson argued that the amount of deviation of the particles from their path in the presence of electrical or magnetic field depends upon:

  • the magnitude of the negative charge on the particle, greater the magnitude of the

charge on the particle, greater is the interaction with the electric or magnetic

field and thus greater is the deflection.

The apparatus to determine the charge to the mass ratio of electron

  • the mass of the particle — lighter the particle, greater the deflection.
  • the strength of the electrical or magnetic field — the deflection of electrons from its original path increases with the increase in the voltage across the electrodes, or the strength of the magnetic field.

When only electric field is applied, the electrons deviate from their path and hit the cathode ray tube at point A. Similarly when only magnetic field is applied, electron strikes the cathode ray tube at point C. By carefully balancing the electrical and magnetic field strength, it is possible to bring back the electron to the path followed as in the absence of electric or magnetic field and they hit the screen at point B. By carrying out accurate measurements on the amount of deflections observed by the electrons on the electric field strength or magnetic field strength, Thomson was able to determine the value of e/me as:

Emₑ  = 1.758820 × 1011 C kg–1

Where me is the mass of the electron in kg and e is the magnitude of the charge on the electron in coulomb (C). Since electrons are negatively charged, the charge on electron is –e

par Claude Foumtum
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