<

Physical chemistry LowerSixth

CHAPTER 5: BOHR’S MODEL FOR THE HYDROGEN ATOM

I. INTRODUCTION

Neils Bohr (1913) was the first to explain quantitatively the general features of hydrogen atom structure and its spectrum. Though the theory is not the modern quantum mechanics, it can still be used to rationalize many points in the atomic structure and spectra. Bohr’s model for hydrogen atom is based on the following postulates:

  1. The electron in the hydrogen atom can move around the nucleus in a circular path of fixed radius and energy. These paths are called orbits, stationary states or allowed energy states. These orbits are arranged concentrically around the nucleus.

The energy of an electron in the orbit does not change with time. However, the electron will move from a lower stationary state to a higher stationary state when required amount of energy is absorbed by the electron or energy is emitted when electron moves from higher stationary state to lower stationary state. The energy change does not take place in a continuous manner

par Claude Foumtum